Click ahead to see some of the best and worst outfits worn by the biggest stars at this year's Venice Film Festival.
Photo by Daniele Venturelli, WireImageCharlize Theron -- BEST
Charlize sparkled in a silver one shoulder Versace gown and diamond bracelets.
Photo by Pascal Le Segretain, WireImageCharlize Theron -- WORST
The Oscar winner's messy tresses and unflattering plum frock failed miserably.
Photo by Daniele Venturelli, WireImageBrad Pitt -- BEST
Nobody sports a sophisticated black tuxedo better than Brad.
Photo by Dominique Charriau, WireImageBrad Pitt -- WORST
Pairing a beige suit with a fugly fedora and green loafers was a major mistake.
Photo by Dominique Charriau, WireImageAnne Hathaway -- BEST
Anne Hathaway wowed the crowd in a strapless sea foam creation courtesy of Atelier Versace.
Photo by Daniele Venturelli, WireImageAnne Hathaway -- WORST
The Get Smart star put us to sleep in this simplistic Lela Rose snoozer.
Photo by Daniele Venturelli, WireImageDiane Kruger -- BEST
Diane Kruger impressed in an elegant black dress, heavenly heels, and a cute coif.
Photo by Lorenzo Santini, Film MagicDiane Kruger -- WORST
Did Diane borrow Brad's hideous hat? That and her wrinkly belted bomb were both busts.
Photo by Pascal Le Segretain, Getty ImagesNatalie Portman -- BEST
Natalie looked perfect in a ravishing Rodarte dress and soft curls.
Photo by Daniele Venturelli, WireImageNatalie Portman -- WORST
The big screen queen missed the mark in a dated 'do and boring blue dress.
Photo by Daniele Venturelli, WireImageEva Herzigova -- BEST
Eva channeled Old Hollywood in her glamorous white ensemble and magnificent makeup.
Photo by Pascal Le Segretain, Getty ImagesEva Herzigova -- WORST
The Czech supermodel deserted her sense of style in an outrageously awful outfit.
Photo by Daniele Venturelli, WireImageTilda Swinton -- BEST
Tilda kept it classy in a muted mustard goddess gown and minimal jewels.
Photo by George Pimentel, WireImageTilda Swinton -- WORST
The reigning Best Supporting Actress winner flopped in this unforgivable fashion faux pas.
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