Hot-and-cool blonde Emma Caulfield bedeviled fans of TV's "Buffy the Vampire Slayer" when she first appeared as the demon Anyanka in 1999; her popularity proved so formidable, series creator Joss Wheadon added her to the show's regular cast a season later, reborn in the form human Anya Emerson. Caulfield, who earned a degree in psychology from San Francisco State University,…
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